Advanced Polymer Chemistry by Chanda

By Chanda

This quantity employs a pragmatic, problem-solving method of realizing the unique chemistry, kinetics and mechanisms of polymer synthesis. It offers a accomplished research of the tools of synthesis and methods of characterization designated to polymers. There are over 2000 equations, literature references, drawings, illustrative examples, workouts, and worked-out difficulties and solutions to enhance crucial ideas mentioned during the textual content.

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4(a)], CsHs 5×12 + 8×1 = 58g/mol Accordingto representation in Fig. 4(b), each sulfide cross-link joins two isoprene units. With x = 2, one sulfur atom, on the average, is required for cross-linking per isoprene repeating unit. 4 Vulcanization of natural rubber with sulfur. (a) Linear polyisoprene (natural rubber). (b) An idealized structure produced by vulcanization with fi~r. The number(x) of sulfur atoms in sulfide cross-linkages is 1 or 2 in efficient vulcanization systems but may be as high as 8 under conditions where cyclic and other structures are also formedin the reaction.

E. Jr. PolymerChemistry, an Introduction. Marcel Dekker, NewYork (1981). 1. 2. 3. 4. 5. 6. What is the acid equivalent of polycaprolactam (nylon-6) with average D_P 500 ? 7. Howwould you determine experimentally whether the polymerization of an unknown monomer was proceeding by a step or a chain mechanism ? 8. (a) What is the functionality of the diglycidyl ether of bisphenol A (I) hardening reaction with diethylene triamine (II)? 9. Each of the following polymers can be synthesized from different monomers (a) -{--O(CH2)sCO--}-¢-~ (b) -(-OCH2 CH2CH2--)w(c) --[--NH-( CH2) 7-CO-]~-,~ Show by equations the overall chemical reactions involved in the synthesis of these polymers.

PolymerChemistry, The Basic Concepts. Marcel Dekker, NewYork (1984). Odian G. Principles of Polymerization. 3rd ed. Chap. 1. John Wiley, NewYork (1991). Rudin A. The Elements of PolymerScience and Engineering. Chap. 1. Academic Press, NewYork (1982). SeymourR. B. and Carraher C. E. Jr. PolymerChemistry, an Introduction. Marcel Dekker, NewYork (1981). 1. 2. 3. 4. 5. 6. What is the acid equivalent of polycaprolactam (nylon-6) with average D_P 500 ? 7. Howwould you determine experimentally whether the polymerization of an unknown monomer was proceeding by a step or a chain mechanism ?

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